Check out photos of Justin Timberlake
"It's great to be married, the ceremony was beautiful and it was so special to be surrounded by our family and friends," the pair told the magazine in a statement.
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Guests included Andy Samberg and Biel's 7th Heaven co-star Beverley Mitchell, who were photographed at a pre-wedding bash earlier this week.
Check out photos of Jessica Biel
Timberlake, 31, and Biel, 30, have been dating since 2007 and briefly split last year before reuniting. They got engaged in December.
This is the first marriage for both. Timberlake previously dated Britney Spears and Cameron Diaz, and Biel dated her Cellular co-star Chris Evans.